Information cascades are ubiquitous in both physical society and online social media, taking on large variations in structures, dynamics and semantics. Although the dynamics and semantics of information cascades have been studied, the structural patterns and their correlations with dynamics and semantics are largely unknown. Here we explore a large-scale dataset including $432$ million information cascades with explicit records of spreading traces, spreading behaviors, information content as well as user profiles. We find that the structural complexity of information cascades is far beyond the previous conjectures. We first propose a ten-dimensional metric to quantify the structural characteristics of information cascades, reflecting cascade size, silhouette, direction and activity aspects. We find that bimodal law governs majority of the metrics, information flows in cascades have four directions, and the self-loop number and average activity of cascades follows power law. We then analyze the high-order structural patterns of information cascades. Finally, we evaluate to what extent the structural features of information cascades can explain its dynamic patterns and semantics, and finally uncover some notable implications of structural patterns in information cascades. Our discoveries also provide a foundation for the microscopic mechanisms for information spreading, potentially leading to implications for cascade prediction and outlier detection.