The present study proposed a method for numerical solution of linear Volterra integral equations (VIEs) of the third kind, before only analytical solution methods had been discussed with reference to previous research and review of the related literature. Given that such analytical solutions are not almost always feasible, it is required to provide a numerical method for solving the mentioned equations. Accordingly, Krall-Laguerre polynomials were utilized for numerical solution of these equations. The main purpose of this method is to approximate the unknown functions through Krall-Laguerre polynomials. Moreover, an error analysis is performed on the proposed method.