Artificial neural networks (ANNs) are commonly labelled as black-boxes, lacking interpretability. This hinders human understanding of ANNs' behaviors. A need exists to generate a meaningful sequential logic for the production of a specific output. Decision trees exhibit better interpretability and expressive power due to their representation language and the existence of efficient algorithms to generate rules. Growing a decision tree based on the available data could produce larger than necessary trees or trees that do not generalise well. In this paper, we introduce two novel multivariate decision tree (MDT) algorithms for rule extraction from an ANN: an Exact-Convertible Decision Tree (EC-DT) and an Extended C-Net algorithm to transform a neural network with Rectified Linear Unit activation functions into a representative tree which can be used to extract multivariate rules for reasoning. While the EC-DT translates the ANN in a layer-wise manner to represent exactly the decision boundaries implicitlylearned by the hidden layers of the network, the Extended C-Net inherits the decompositional approach from EC-DT and combines with a C5 tree learning algorithm to construct the decision rules. The results suggest that while EC-DT is superior in preserving the structure and the accuracy of ANN, Extended C-Net generates the most compact and highly effective trees from ANN. Both proposed MDT algorithms generate rules including combinations of multiple attributes for precise interpretation of decision-making processes.