This paper presents a distributed multi-layer ring barrier coverage algorithm. In order to achieve single-layer ring barrier coverage, a distributed single-layer ring barrier coverage algorithm that maximises the probability of monitoring is proposed. Considering the security risks of single-layer barrier coverage, a distributed adjustment mechanism between multiple layers of barriers is designed and combined with the single-layer ring barrier coverage algorithm to propose a distributed multi-layer ring barrier coverage algorithm. Furthermore, we present a theoretical analysis of the proposed algorithm to demonstrate its effectiveness and necessity. Finally, our algorithm is verified by numerical simulation and experiment.