Audio-visual zero-shot learning aims to recognize unseen categories based on paired audio-visual sequences. Recent methods mainly focus on learning aligned and discriminative multi-modal features to boost generalization towards unseen categories. However, these approaches ignore the obscure action concepts in category names and may inevitably introduce complex network structures with difficult training objectives. In this paper, we propose a simple yet effective framework named Knowledge-aware Distribution Adaptation (KDA) to help the model better grasp the novel action contents with an external knowledge base. Specifically, we first propose using large language models to generate rich descriptions from category names, which leads to a better understanding of unseen categories. Additionally, we propose a distribution alignment loss as well as a knowledge-aware adaptive margin loss to further improve the generalization ability towards unseen categories. Extensive experimental results demonstrate that our proposed KDA can outperform state-of-the-art methods on three popular audio-visual zero-shot learning datasets. Our code will be avaliable at \url{https://github.com/chenhaoxing/KDA}.